Dynamic equilibrium

Photo of an elephant balancing on a rock

Aims of this page

After studying this page, you should be able to:

Open and closed systems

When you carry out a chemical reaction:

  • the reactants and products form the system
  • the container and everything form the environment.

Chemical reactions can happen in two types of system:

  • an open system – substances can enter or leave
  • a closed system – substances cannot enter or leave.

Closed systems include reactions involving solutions in a beaker or test tube, and reactions involving gases in a container with a closed lid.

Photo showing two colourless liquids being mixed and forming a cloudy yellow substance.
This precipitation reaction happens in a closed system. Even though the beakers have no lids, the reaction itself is contained within the liquids.

Reaching equilibrium

Reversible reactions that happen in closed systems eventually reach a dynamic equilibrium. At this point:

  • the forward and reverse reactions still carry on (dynamic), but
  • they happen at an equal rate, and so
  • the concentrations of all reacting substances do not change (equilibrium).

The video below shows a young girl walking the wrong way on a travelator. Notice that:

  • she stays in the same position when she walks at the same speed as the travelator, just like a chemical reaction at equilibrium
  • she moves towards or away from the camera when she speeds up or slows down.
Reaching equilibrium from a starting mixture of reactants without products

Dynamic equilibrium

Reversible reactions that happen in closed systems eventually reach a dynamic equilibrium. At this point:

  • the forward and reverse reactions still carry on (dynamic), but
  • they happen at an equal rate, and so
  • the concentrations of all reacting substances do not change (equilibrium).
Reaching equilibrium from a starting mixture of reactants without products

The video below shows a young girl walking the wrong way on a travelator. Notice that:

  • she stays in the same position when she walks at the same speed as the travelator, just like a chemical reaction at equilibrium
  • she moves towards or away from the camera when she speeds up or slows down.